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Why is mCPBA used in epoxidation?

Why is mCPBA used in epoxidation?

A white solid, it is used widely as an oxidant in organic synthesis. mCPBA is often preferred to other peroxy acids because of its relative ease of handling. mCPBA is a strong oxidizing agent that may cause fire upon contact with flammable material.

What is the product of Baeyer Villiger reaction?

The Baeyer–Villiger oxidation is an organic reaction that forms an ester from a ketone or a lactone from a cyclic ketone, using peroxyacids or peroxides as the oxidant….Baeyer–Villiger oxidation.

Baeyer-Villiger oxidation
Organic Chemistry Portal baeyer-villiger-oxidation
RSC ontology ID RXNO:0000031

What is the role of mCPBA?

mCPBA is widely used for chemical transformations such as the oxidation of carbonyl compounds, iminoindolines, olefins, imines, alkanes, silyl enol ethers, N- and S-heterocycles, active methylene groups, fluoromethylated allylic bromides, cyclic acetals, N-substituted phthalimidines, selenides, furans and phosphates.

What is the work of mCPBA?

Which reagent is used in Baeyer Villiger rearrangement?

* The reagents which can be employed in Baeyer villiger oxidation include: Metachloroperbenzoic acid (MCPBA) – A popular and most versatile reagent for BV rearrangement and epoxidation reactions, Peroxyacetic acid (PAA), Peroxytrifluoroacetic acid (TFPAA)

What happens when acetophenone is treated with mCPBA?

When an acetophenone is treated with a peracid (e.g. mCPBA), two distinct oxidation mechanisms can take place: (1) the direct hydroxylation of the benzene ring as previously described in an account from our laboratory,9 a mechanism that we believe involves a direct HO+ transfer from peracid [R–C(=O)OOH] to the benzene …

What does mCPBA stand for?

meta-chloroperoxybenzoic acid
Illustrated Glossary of Organic Chemistry – mCPBA (meta-chloroperoxybenzoic acid) mCPBA (meta-chloroperoxybenzoic acid): A peracid derived from meta-chlorobenzoic acid. An oxidant; converts an alkene to an epoxide, and a thioether to a sulfoxide, and then to a sulfone.

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